What you are looking at
A single electron circles a positively charged nucleus, but — unlike a planet, which could orbit at any
distance — it is allowed only a discrete set of
shells labelled n = 1, 2, 3, … On the right
is the matching
energy-level diagram, and along the bottom is the
emission
spectrum: the specific colours this atom can give off. Send the electron to a new level and watch a
photon fly out (jumping down) or get absorbed (jumping up).
Bohr's quantum leap
In 1913 Niels Bohr proposed three rules that broke with classical physics. First, the electron occupies only
certain
stationary states with quantized angular momentum, and — crucially — does
not radiate while in them (classically an orbiting charge should spiral inward and the atom
collapse). Second, each state has a fixed energy:
Eₙ = −13.6 · Z² / n² eV
negative because the electron is bound, approaching 0 as n → ∞ (free). The orbit radius grows as
rₙ = n²a₀/Z, with a₀ = 0.053 nm the Bohr radius. Third, the atom changes energy only by
jumping between levels, emitting or absorbing one photon whose energy exactly bridges the gap:
ΔE = Eᵢ − E_f = h f = h c / λ
Why atoms have line spectra
Because only certain energy gaps exist, an atom emits only certain wavelengths — sharp
spectral
lines, not a continuous rainbow. For hydrogen these fall into series named by the final level:
Lyman (down to n = 1, ultraviolet),
Balmer (to n = 2, visible — the four
coloured lines on the strip), and
Paschen (to n = 3, infrared). The wavelengths obey the
Rydberg formula 1/λ = R(1/n_f² − 1/n_i²). These fingerprints are how we identify elements in stars.
Things to try
Excite the electron to a high level and let it cascade down, watching each photon's colour. Find the Balmer
lines (any jump landing on n = 2) and see them line up with the coloured spectrum below. Increase the
nuclear charge Z for hydrogen-like ions (He⁺, Li²⁺): every energy deepens by Z² and the
orbits shrink, pushing the spectrum toward the ultraviolet. Bohr's model works beautifully for one electron
but fails for many-electron atoms — the door it opened led to full quantum mechanics.